Diels–Alder Reactions Between Hexafluoro-2-Butyne and bis-Furyl Dienes: Kinetic versus Thermodynamic Control Научная публикация
Журнал |
Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X |
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Вых. Данные | Год: 2018, Том: 54, Номер: 23, Страницы: 2850-2853 Страниц : 4 DOI: 10.1039/c7cc09466c | ||||||||
Ключевые слова | ACETYLENEDICARBOXYLIC ACID; CYCLOADDITIONS; TANDEM; DOMINO; SYSTEMS; N,N'-DIPYRROLYLMETHANE; MECHANISMS; CASCADE; ROUTE; TOOL | ||||||||
Авторы |
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Организации |
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Реферат:
The tandem [4+2] cycloaddition between hexafluoro-2-butyne and bis-furyl dienes, like difurfuryl ester, at room temperature leads to the kinetically controlled “pincer”-adducts – annulated 4a,8a-bis(trifluoromethyl)hexahydro-1,4:5,8-diepoxynaphthalenes. On the other hand, if these reactions proceed at 140 °C, only the thermodynamically controlled “domino”-adducts – annulated 2,3-bis(trifluoromethyl)hexahydro-1,4:5,8-diepoxynaphthalenes – are formed. Therefore, a very rare and unexpected example of full kinetic and thermodynamic control in the Diels–Alder reaction is reported in this paper.
Библиографическая ссылка:
Borisova K.K.
, Nikitina E.V.
, Novikov R.A.
, Khrustalev V.N.
, Dorovatovskii P.V.
, Zubavichus Y.V.
, Kuznetsov M.L.
, Zaytsev V.P.
, Varlamov A.V.
, Zubkov F.I.
Diels–Alder Reactions Between Hexafluoro-2-Butyne and bis-Furyl Dienes: Kinetic versus Thermodynamic Control
Chemical Communications. 2018. V.54. N23. P.2850-2853. DOI: 10.1039/c7cc09466c WOS Scopus РИНЦ CAPlusCA OpenAlex
Diels–Alder Reactions Between Hexafluoro-2-Butyne and bis-Furyl Dienes: Kinetic versus Thermodynamic Control
Chemical Communications. 2018. V.54. N23. P.2850-2853. DOI: 10.1039/c7cc09466c WOS Scopus РИНЦ CAPlusCA OpenAlex
Файлы:
Полный текст от издателя
Даты:
Поступила в редакцию: | 9 дек. 2017 г. |
Принята к публикации: | 24 янв. 2018 г. |
Опубликована online: | 2 февр. 2018 г. |
Опубликована в печати: | 21 мар. 2018 г. |
Идентификаторы БД:
Web of science: | WOS:000428844500005 |
Scopus: | 2-s2.0-85044057322 |
РИНЦ: | 35514270 |
Chemical Abstracts: | 2018:229038 |
Chemical Abstracts (print): | 168:346635 |
OpenAlex: | W2785478358 |