XAS Study of Americium Complexes with Calixarene Bearing Carbamoylmethylphosphine Oxide Moieties Full article
Journal |
Mendeleev Communications
ISSN: 0959-9436 , E-ISSN: 1364-551X |
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Output data | Year: 2021, Volume: 31, Number: 2, Pages: 188-190 Pages count : 3 DOI: 10.1016/j.mencom.2021.03.014 | ||||||||
Tags | liquid–liquid extraction, EXAFS spectroscopy, calixarenes, americium complexes, phosphorylacetamides, carbamoylmethylphosphine oxides | ||||||||
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Abstract:
The local environment of a novel group of americium (Am3+) complexes with calix[4]arene bearing carbamoylmethylphosphine oxide moieties on the upper rim has been investigated by X-ray absorption spectroscopy. The complexes were obtained by the extraction of americium from aqueous nitric or 2-(1-adamantyl)sulfoacetic acids with the 1,2-dichloroethane solution of this ligand. The correlation of the structures of the obtained complexes with americium distribution coefficients in the corresponding extraction systems is revealed.
Cite:
Putkov A.E.
, Vasiliev A.N.
, Zubavichus Y.V.
, Teterin Y.A.
, Ivanov K.E.
, Trigub A.L.
, Kovalev V.V.
, Vatsouro I.M.
XAS Study of Americium Complexes with Calixarene Bearing Carbamoylmethylphosphine Oxide Moieties
Mendeleev Communications. 2021. V.31. N2. P.188-190. DOI: 10.1016/j.mencom.2021.03.014 WOS Scopus РИНЦ AN OpenAlex
XAS Study of Americium Complexes with Calixarene Bearing Carbamoylmethylphosphine Oxide Moieties
Mendeleev Communications. 2021. V.31. N2. P.188-190. DOI: 10.1016/j.mencom.2021.03.014 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: | Nov 19, 2020 |
Published print: | Mar 1, 2021 |
Published online: | Mar 31, 2021 |
Identifiers:
Web of science: | WOS:000635839800014 |
Scopus: | 2-s2.0-85104972745 |
Elibrary: | 46029974 |
Chemical Abstracts: | 2021:812286 |
OpenAlex: | W3152286324 |