Synthesis and Investigations of Chiral NNO Type Copper(II) Coordination Polymers Full article
Journal |
ChemistrySelect
, E-ISSN: 2365-6549 |
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Output data | Year: 2018, Volume: 3, Number: 2, Pages: 653-656 Pages count : 3 DOI: 10.1002/slct.201702689 | ||||||
Tags | Aldol reaction, Coordination polymers, Copper, N,O ligands, Tridentate ligands | ||||||
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Abstract:
Herein, we report the synthesis and characterizations of chiral copper(II) coordination polymers (CPs) based on Schiff base of (S)‐2‐aminomethylpyrrolidine and salicylaldehyde derivatives. Single crystal X‐ray analysis showed that copper(II) complex is 1D CP, with the repeating units LCu‐OAc (L=ligand) organized in a perpendicular manner, where the copper(II) atoms are six‐coordinated and have a distorted octahedral geometry. Also complex with chlorine counter ion having unusual dimeric structure was synthesized and characterized. It was demonstrated that CPs catalyze the enantioselective Henry reaction with up to 78% ee.
Cite:
Larionov V.A.
, Yashkina L.V.
, Smol’yakov A.F.
, Zubavichus Y.V.
, Babievsky K.K.
, Akat’yev N.V.
, Titov A.
, Belokon Y.N.
, Maleev V.I.
Synthesis and Investigations of Chiral NNO Type Copper(II) Coordination Polymers
ChemistrySelect. 2018. V.3. N2. P.653-656. DOI: 10.1002/slct.201702689 WOS Scopus РИНЦ AN OpenAlex
Synthesis and Investigations of Chiral NNO Type Copper(II) Coordination Polymers
ChemistrySelect. 2018. V.3. N2. P.653-656. DOI: 10.1002/slct.201702689 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: | Nov 10, 2017 |
Accepted: | Dec 29, 2017 |
Published online: | Jan 11, 2018 |
Published print: | Jan 17, 2018 |
Identifiers:
Web of science: | WOS:000422674700044 |
Scopus: | 2-s2.0-85043720341 |
Elibrary: | 35526351 |
Chemical Abstracts: | 2018:89209 |
OpenAlex: | W2783569357 |